Synthesis and characterization of tin oxide nanoparticles by. It also shows that the diffraction peak are broadened which reveals the narrow size distribution of the cobalt oxide nanoparticles. Hydrothermal synthesis of cobalt oxide nanoparticles 343 presence of triton x100 as surfactant, and koh and h2o2 as homogeneous precipitating agents. First, the nickel ii schiff base precursor was prepared by solidstate grinding using nickel ii nitrate hexahydrate, nino 3 26h 2 o, and the schiff. The study was focused on different metal oxide particles cuo, tio 2, zno, cuznfe 2 o 4, fe 3 o 4, fe 2 o 3, and the toxicity was compared to that of carbon nanoparticles and multiwalled carbon nanotubes mwcnt. Because of the magnetic properties of tin oxide nanoparticles are used in magnetic data storage and magnetic resonance imaging. Nickel oxide nio nanoparticles prepared by solidstate. Size dependent antibacterial activity of cobalt oxide nanoparticles by heba awad izzat maloul supervisor dr. Characterization of cobalt oxide co 3 o 4 nanoparticles prepared by various methods. Goldoxidecontaining nanoparticles have been produced in a range of partial to full oxidation conditions, where the nanoparticle electronic structure and stoichiometry have been characterized. Each crystalline domain is characterized by its own magnetic moment oriented randomly. Introduction in recent years, nickel oxide nanoparticles have been extensively investigated due to their properties 1 and potential. Copper is a block d, period 4 element, while oxygen is a block p, period 2 element.
Hussein 2,3 1department of chemistry, faculty of science, annajah national university, nablus, palestine. The particle size is determined from xray diffraction studies and tem image. Cobalt is a block d, period 4 element, while oxygen is a block p, period 2 element. The samples were characterized by xray diffraction, fourier transform infrared spectroscopy, scanning electron microscope, and transmission electron microscopy. Further its antimicrobial activity against bacillus subtilis and. This article discusses about the properties and applications of copper oxide nanoparticles. Metal oxide nanoparticles brookhaven national laboratory. We studied the structural and antimicrobial properties of copper oxide nanoparticles cuo nps synthesized by a very simple precipitation technique. The particles may incorporate other substances, asfor example diphenylalanine cobalt oxide hybrid nanowires. Scientific research and development supplier details. Cobalt iron oxide nanoparticles nanopowder american. The lifecycle of inorganic nanoparticles nps in the body and potentially associated health risks still raise serious concerns. The human lung epithelial cell line a549 was exposed to the particles, and cytotoxicity was analyzed using trypan blue staining. Cobalt ii oxide nanopowder nanoparticles coo, cobalt ii oxide nanoparticles.
Synthesis and characterisation of copper oxide nanoparticles. Short communication chemical synthesis of cobalt oxide co. Cobalt oxide nanoparticles are made of small crystalline domains. O cuprous oxide and cuo cupric oxide are two important oxide compounds of copper. The effect of sintering on the particle size is analyzed. Metal oxide nanoparticles have wide applications, primarily in the technology. A freshwater microalga strain of chlorella vulgaris was used to investigate toxic effects induced by nickel oxide nanoparticles nionps in suspension. Cobalt oxide nanoparticles high purity fast delivery.
Pure co 3 o 4 nanoparticles with diameters 3050 nm are fabricated from nn. Cobalt oxide nanoparticles appear as a white powder with spinel crystal structure. Iron oxide and cobalt oxide nanomaterials have been growing excessive importance because of their magnetic characteristics and wide applications. Field emission scanning electron microscope fesem and field emission. Physiological remediation of cobalt ferrite nanoparticles by.
This article discusses the properties and applications of cobalt oxide nanoparticles. Characterization was done by xray diffraction xrd analysis, scanning. A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1. A known quantity of hydrated stannic chloride solution is taken in a beaker and the surfactant tritonx100 measuring 5% of the volume of the solution is added and stirred it for 40 minutes using. Hosseini1 1 chemistry department of imam hussein university, tehran, i. This chapter covers the fundamental science, synthesis, characterization, physico chemical properties and applications of oxide nanomaterials. Waghuley department of physics, sant gadge available online at. Synthesis and optical characterization of copper oxide. Hydrothermal synthesis of cobalt oxide nanoparticles. Copper oxide nanoparticles prepared by solid state thermal. Copper oxide cuo nanopowder nanoparticles us research nanomaterials, inc. Copper oxide nanoparticles prepared by solid state thermal decomposition.
The total magnetic moment of the nanoparticles is the sum of these magnetic domains coupled by dipolar interactions. Pdf synthesis, characterization, and antimicrobial activity. This article is published with open access at abstract in this study. Optical, electrical and structural studies of nickelcobalt. As is the case for many nanomaterials, cobolt oxide nanopowders have been utilized as catalysts and catalyst carriers for a variety of reasons. Hollow nanospheres of cobalt oxide have been investigated as materials for gas sensor electrodes, for the detection of toluene, acetone, and other organic vapors. Tin oxide definition of tin oxide by merriamwebster. The result concludes that the cobalt oxide nanoparticles have higher activity for the detection of nitrobenzene.
Nickel ii schiff base precursor, nio nanoparticles, prepared, sem, tem, xrd. Synthesis and characterization of cobalt nanoparticles using. Nanoscale cobalt iron oxide particles are typically 1030 nanometers nm with specific surface area ssa in the 150 m 2 g range. Synthesis and optical characterization of copper oxide nanoparticles amrut. Copper oxide nanoparticles appear as a brownishblack powder. It has excellent antimicrobial activity against various bacterial strains 2. Hydrothermal synthesis of cobalt oxide nanoparticles 341 optical and vsm studies the optical absorption spectra of the co3o4 nanoparticles have been carried out using uvvis spectroscopy. Synthesis of metal oxide nanoparticles for superconducting. Short communication chemical synthesis of cobalt oxide co k. Since last few years, synthesis of nanoparticles has been attracted considerable attention. Each is a fine powder composed of particles of cobalt oxide smaller than 100nm in diameter, but from there they vary in properties and applications.
Zinc oxide nanoparticles synthesis from moringa oleifera. Synthesis, characterization, and antimicrobial activity of copper oxide nanoparticles article pdf available in journal of nanomaterials 20143. Thermal and microwave methodologies are used to synthesize different metal oxides nanoparticles such as magnetite fe3o4, cerium oxide. Cobalt can be found in cobaltite, erythrite, glaucodot and skutterudite ores. Abstractmetal and metal oxide particles are intensively pursued because of their prominence in different fields of applications in science and technology. The copper oxide nanoparticles cuonps possess a wide range of applications. Size dependent antibacterial activity of cobalt oxide. The sem image of cobalt oxide nanoparticles shows the nanosized agglomerated particles. Synthesis and characterization of cobalt oxide nanoparticles. Synthesis and characterization of cobalt nanoparticles prepared by liquidphase reduction by mary donnabelle l. Characterization of cobalt oxide co o nanoparticles. Xray diffraction patter xrd pattern showed the crystalline nature of cuo nps. Nickel oxide nio nanoparticles were successfully synthesized by the reaction of nickel chloride with hydrazine at room temperature and thermal decomposition of the precursor nickel hydroxide ni. Cobalt ii oxide nanopowder nanoparticles coo, co3o4 nanoparticles nanopowder us research nanomaterials, inc.
Synthesis and characterization of tin oxide nanoparticles. The utilization of plants in synthesis of zinc oxide nanoparticles zno nps is quite. Cobaltii oxide nanoparticles nanopowder american elements. Zinc oxide nanoparticles synthesis from moringa oleifera lam. The effect of citric acid additives on the formation and growth mechanism of cobalt nanoparticles was investigated using polarization methods. Iron oxideand cobalt oxide nanoparticles are prepared by using different methods, precursors, solveemperature conditions. Colloidal polymerization of polymercoated ferromagnetic.
Cobalt iron oxide nanoparticles, nanodots or nanopowder are spherical high surface area metal particles. Algal cells were exposed during 96 h to 0100 mg l1 of nionps and analyzed by flow cytometry. Preparation of copper oxide nanoparticles and its application. Tin oxide sno2 nanoparticles, as one of the most important semiconductor oxides, has been used as photo catalyst for photo degradation of organic compounds. Synthesis and characterization of cobalt nanoparticles. Effect of calcination temperatures on size, dimension and catalytic decomposition of hydrogen peroxide s. Physiological remediation of cobalt ferrite nanoparticles. Synthesis and characterization of copper oxide nanoparticles. Results the typical xrd pattern of thecuo nanoparticles annealed at 300c is shown in figure 1.
The ftir studies have been used to confirm the formation of metal oxide. Copper oxide cuo nanoparticles properties, applications. Cobaltii oxide nanoparticles nanopowder product number. Nano cobalt iron oxide particles are also available in passivated and in ultra high purity and high purity and carbon coated and dispersed forms. Cobalt oxide nanoparticles serve as vital inorganic material with a variety of applications. Sep, 2015 in this study, cupric oxide cuo nanoparticles were synthesized via sonochemical method. Cobalt oxide nanoparticles, such as nanotubes, offer high surfacetovolume ratio and short path length for lithium cation transport, leading to high reversible capacity and good cycle life. Nanoparticles of nickelcobalt oxide are prepared by chemical coprecipitation method. The precursors of copper oxide were first prepared in a continuous mode through a liquidliquid reaction using copper ii sulfate pentahydrate and sodium carbonate as reactants. Pdf copper oxide nanoparticles synthesis, properties and. Ambedkar college, chandrapur 442 401, india 2department of electronics, r. Optical, electrical and structural studies of nickel. Characterization and its electrocatalytic activity towards nitrobenzene.
Karlsson, pontus cronholm, johanna gustafsson and lennart moller unit for analytical toxicology, department of biosciences and nutrition at novum, karolinska institutet, se141 57 huddinge, stockholm, sweden. Cobalt oxide nanoparticles used in temperature and gas sensors. Received 22 nd march abstract in the present work, cobalt oxide co 3o4 nanoparticles were synthesized by co of asprepared nanoparticles was confirmed by using x. The second part describes the role of astrocytes as a central key player in the brain homeostasis chapter 1. Synthesis of copper oxide nanoparticles using simple. Sunscreens with titanium dioxide as nanoparticles europa eu. Many applications of engineered cerium oxide nanoparticles naturally disperse. Synthesis and spectral studies of interactions with glucose article pdf available in materials science in semiconductor processing 166. Cobalt nanoparticles were produced by employing the liquidphase reduction method and hydrazine. They are characterized by ftir, xrd, sem and tem techniques. Copper ii acetate was used as a precursor and sodium hydroxide as a reducing agent. In this study, cupric oxide cuo nanoparticles were synthesized via sonochemical method.
Balela thesis submitted in fulfillment of the requirements for the degree of master of science july 2008. Cobalt oxide particles may be anchored on substrates such as graphene to improve the dimensional stability of the anode and to prevent particle aggregation during lithium charge and discharge processes gas sensor. Gold oxide nanoparticles with variable gold oxidation. Its optical and magnetic properties article pdf available september 2014 with 2,341 reads how we measure reads. The spherical cuo nanoparticles were dispersed in sodium hexametaphosphate under sonication 25 khz to analyze the particle size. Iron oxide nanoparticles for biomedical applications. Wastewater disinfection by synthesized copper oxide nanoparticles stabilized with surfactant mohammed suleiman 1, muath mousa 1, amjad i. In this paper, platelike nio nanoparticles were prepared by onepot solidstate thermal decomposition of nickel ii schiff base complex as new precursor. Mohammed suleiman abstract one of the major health problems that has been showing up recently, was due to the emergence of new bacterial strains that posses resistant to. The electrochemical detection of nitrobenzene nb by cobalt oxide nanoparticles was investigated by cyclic voltammetry. Compared with ordinary copper oxide powder, the nanoparticles of copper oxide show superior catalytic activity and selectivity. We report the synthesis of copper oxide cuo nanoparticles from cuno32 through wet chemical precipitation method. The aim of this research was to synthesize copper oxide nanoparticles, which were then applied to prepare cuowater nanofluid, using a spinning disk reactor sdr.
Study of structural and optical properties of cupric oxide. Using a combination of dipolar nanoparticle assembly and a solution oxidation of preorganized metallic colloids, interconnected nanoparticles of cobalt oxide spanning micrometers in length were prepared. Original article study of structural and optical properties of cupric oxide nanoparticles n. Pdf hydrothermal synthesis of cobalt oxide nanoparticles. The deposition of the oxidized nanoparticles has showed that the species assigned as containing lower oxide could be preserved in the landing and then studied on a substrate for a limited time. The present investigation reports, the synthesis and characterization of cobalt oxide co 3 o 4 nanoparticles using thermal treatment. The possible lower oxide formation in nanoparticles is discussed in connection to the enhanced catalytic activity of gold nanoparticles.
The co3o4 nanoparticles are spherical shaped with an average size 26. Semiconducting materials have been particularly interesting because of their great practical importance in. The ph of the solution plays an important role in the synthesis of copper oxide nanoparticles. Our results indicate that with the increase of the oxidation degree in these nanoparticles the gold oxidation state possibly changes from lower oxides with mono or divalent metal to the higher oxide. Synthesis of copper oxide nanoparticles using simple chemical route jyoti mayekar, vijay dhar, s. Synthesis and characterization ensieh shahsavani 1, nourollah feizi, aliakbar dehno khalaji2 1department of chemistry, payame noor university, p. The preparation of polystyrenecoated cobalt oxide nanowires is reported via the colloidal polymerization of polymercoated ferromagnetic cobalt nanoparticles psconps. Tin oxide definition is either of two oxides of tin. Cobalt oxide co3o4 nanoparticles properties, applications. Synthesis, characterization, and antimicrobial activity of. Synthesis and impregnation of copper oxide nanoparticles on. Gold oxide nanoparticles with variable gold oxidation state. Nanoparticles of nickel cobalt oxide are prepared by chemical coprecipitation method.
Wastewater disinfection by synthesized copper oxide. Synthesis of copper oxide nanoparticles using simple chemical. A known quantity of hydrated stannic chloride solution is taken in a beaker and the surfactant tritonx100 measuring 5% of the volume of the solution is added and stirred it for 40 minutes using magnetic stirrer to get a homogeneous solution. Study of structural and optical properties of cupric oxide nanoparticles n. They can be reduced to metallic copper when exposed to hydrogen or carbon monoxide under high temperature. All the peaks in diffraction pattern shows monoclinic structure of cuo, and the peaks. Box 193953697,mashhad, iran 2department of chemistry, faculty of science, golestan university, gorgan, iran recieved. Titanium dioxide is used as a uv filter in sunscreen products to protect the skin from harmful. The xrd confirms the crystallinity and crystal structure of the sample. A comparison between metal oxide nanoparticles and carbon nanotubes hanna l. In this article was developed a green synthesis of cuo nanoparticles on vegetal activated carbon. Cuprous oxide is ptype direct band gap ii vi semiconductor 3 with band gap of 2 ev and cupric oxide has a monoclinic structure and presents ptype semiconductor behavior with a. Synthesis of iron oxide, cobalt oxide and silver nanoparticles by different techniques.